Corrosion and Corrosion Properties of Stainless Steels: Part Three
Intergranular corrosion, also called intercrystalline corrosion, occurs on or adjacent to the grain boundaries of a metal. It is caused by microsegregation of impurities and alloying elements on the grain boundaries.
The driving force of intergranular corrosion is the difference between the electrode potentials of the grain boundary and the grain itself, which form a galvanic cell in presence of an electrolyte.