Thermodynamics of TiN Formation in Melts: Part One
In steelmaking process, a strong nitride forming element such as titanium is often added to stabilize nitrogen and improve mechanical properties of steel through the grain refinement during hot rolling.
Recently, the formation of titanium nitride as a secondary inclusion precipitated during solidification received great interest because it is known to help the formation of equi-axed cast structure. On the other hand, titanium nitride formed in liquid steel can agglomerate and cause a nozzle clogging during continuous casting and surface quality problems of final products. In order to control the formation titanium nitride in various grades of steel, it is essential to have accurate thermodynamic data of titanium and nitrogen in steel.